有機構造化学研究室(中村研究室)
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研究業績

原著論文

2024年

Fine-Tuning of the Sequential Self-Assembly of Entangled Polyhedra by Exploiting the Side-Chain Effect
Y. Domoto,* R. Nakabayashi, T. Tsurumi, H. Hayashi, Y. Nakamura, M. Fujita  Chem. Asian J. 2024, e202401378.
DOI: 
10.1002/asia.202401378

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Phenothiazine cyclic hexamers: synthesis, properties, and complexation behavior with C60
K. Yamamoto,* K. Tsutsui, M. Tanuma, K. Ito, K. Wakamatsu, K. Yamamoto, Y. Nakamura,*  Chem. Commun. 2024, 60, 2222-2223.
DOI: 10.1039/D3CC06206F
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2023年

A series of boron difluoride complexes of azinylcarbazoles: synthesis and structure–property relationships
K. Yamamoto,* S. Matsui, S.-i. Kato, Y. Nakamura,*  Org. Biomol. Chem. 2023, 21, 5398-5405.
DOI: 
10.1039/D3OB00795B

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Interconversion of Highly Entangled Polyhedra into Concave Polyhedra by Nitrate-Induced Ternary Coordination
Y. Domoto,* M. Abe, G. R. Genov, Z. Yu, M. Fujita  Angew. Chem. Int. Ed. 2023, 62, e202303714.
Selected as Inside Cover.
DOI: 10.1002/anie.202303714
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Phenothiazine‐, Dihydroacridine‐, and Acridone-Based Boron Difluoride Complexes: Synthesis and Structure−Property Relationships
K. Yamamoto,* W. Imai, S. Kanamori, K. Yamamoto, Y. Nakamura,*  J. Org. Chem. 2023, 88, 4003-4007.
DOI: 10.1021/acs.joc.3c00088
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2022年

Synthesis of Carbazole-containing 1,2-Azaborine Derivatives Using Bora-Friedel–Crafts Reaction and Their Photophysical Properties
K. Yamamoto, I. Yamada, M. Kameyama, Y. Nakamura,*  Chem. Lett. 2022, 51, 65-68.
DOI: 
10.1246/cl.210597

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2021年

Arylene–hexaynylene and –octaynylene macrocycles: Extending the polyyne chains drives self-association by enhanced dispersion force
S.-i. Kato,* R. Kumagai, T. Abe, C. Higuchi, Y. Shiota, K. Yoshizawa, N. Takahashi, K. Ymamamoto, Md Z. Hossain, K. Hayashi, T. Hirose, Y. Nakamura,*  Chem. Commun. 2021, 57, 576-579.
DOI: 
10.1039/d0cc07540j

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2020年

Monoradicals and Diradicals of Dibenzofluoreno[3,2-b]fluorene Isomers: Mechanisms of Electronic Delocalization
H. Hayashi, J. E. Barker, A. C. Valdivia, R. Kishi, S. N. MacMillan, C. J. Gómez-García, H. Miyauchi, Y. Nakamura, M. Nakano,* S.-i. Kato,* J. Casado,*  J. Am. Chem. Soc. 2020, 142, 20444-20455.
DOI: 10.1021/jacs.0c09588

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Visualization of Lipid Droplets in Living Cells and Fatty Livers of Mice Based on the Fluorescence of π-Extended Coumarin Using Fluorescence Lifetime Imaging Microscopy
T. Yoshihara,* R. Maruyama, S. Shiozaki, K. Yamamoto, S.-i. Kato, Y. Nakamura, S. Tobita,*  Anal. Chem. 2020, 92, 4996-5003.
DOI: 10.1021/acs.analchem.9b05184
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Chemical transformations of push–pull fluorenones: push–pull dibenzodicyanofulvenes as well as fluorenone– and dibenzodicyanofulvene–tetracyanobutadiene conjugates
S.-i. Kato,* T. Kijima, Y. Shiota, T. Abe, S. Kuwako, H. Miyauchi, N. Yoshikawa, K. Yamamoto, K. Yoshizawa, T. Yoshihara, S. Tobita, Y. Nakamura,*  Org. Biomol. Chem. 2020, 18, 4198-4209.
DOI: 
10.1039/c9ob02706h
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2018年

2,4,5,7,9,10-Hexaethynylpyrenes: Synthesis, Properties, and Self-assembly
S.-i. Kato,* H. Kano, K.-i. Irisawa, R. Yamamoto, C. Kitamura, D. Nara, T. Yamanobe, H. Uehara, Y. Nakamura,*  Org. Lett. 2018, 20, 7530-7534.
DOI: 
10.1021/acs.orglett.8b03290

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Trithiazolyl-1,3,5-triazines bearing decyloxybenzene moieties: synthesis, photophysical and electrochemical properties, and self-assembly behavior
S.-i. Kato, S. Jin, T. Kimura, N. Yoshikawa, D. Nara, K. Imamura, Y. Shiota, K. Yoshizawa, R. Katoono, T. Yamanobe, H. Uehara, Y. Nakamura,*  Org. Biomol. Chem. 2018, 16, 3584-3595.
DOI: 10.1039/c8ob00471d
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Synthesis of isomeric coumarin-fluorene hybrids by photocyclization and the photophysical features
M. Yamaji,* H. Okamoto, K. Goto, S.-i. Kato, F. Tani, Y. Nakamura,  Tetrahedron Lett. 2018, 59, 1216-1219.
DOI: 10.1021/acs.inorgchem.7b02013
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2017年

Blue Fluorescence from BF2 Complexes of N,O-Benzamide Ligands: Synthesis, Structure, and Photophysical Properties
M. Yamaji,* S.-i. Kato, K. Tomonari, M. Mamiya, K. Goto, H. Okamoto, Y. Nakamura, F. Tani,  Inorg. Chem. 2017, 56, 12514-12519.
DOI: 
10.1021/acs.inorgchem.7b02013

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Tetraalkoxyphenanthrene-Fused Hexadecadehydro[20]- and Tetracosadehydro[30]annulenes: Syntheses, Aromaticity/Antiaromaticity, Electronic Properties, and Self-Assembly
N. Takahashi, S.-i. Kato, M. Yamaji, M. Ueno, R. Iwabuchi, Y. Shimizu, M. Nitani, Y. Ie, Y. Nakamura,* J. Org. Chem. 2017, 82, 8882-8896.
DOI: 10.1021/acs.joc.7b01165
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Tetraalkoxyphenanthrene-Fused Thiadiazoloquinoxalines: Synthesis, Electronic, Optical, and Electrochemical Properties, and Self-Assembly
S.-i. Kato, K. Watanabe, M. Tamura, M. Ueno, M. Nitani, Y. Ie, Y. Aso, T. Yamanobe, H. Uehara, Y. Nakamura,* J. Org. Chem. 2017, 82, 3132-3143.
DOI: 
10.1021/acs.joc.7b00084

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2016年

Photochemical Synthesis and Photophysical Features of Ethynylphenanthrenes Studied by Emission and Transient Absorption Measurements
Y. Hakoda, M. Aoyagi, K. Irisawa, S.-i. Kato, Y. Nakamura, M. Yamaji,* Photochem. Photobiol. Sci. 2016,15, 1586.
DOI: 10.1039/C6PP00291A

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Benzo- and Naphthopentalenes: Syntheses, Structures, and Properties
S.-i. Kato, S. Kuwako, N. Takahashi, T. Kijima, Y. Nakamura,* J. Org. Chem. 2016
, 81, 7700.
DOI: 10.1021/acs.joc.6b01409

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Push‒Pull Fluorenones and Benzazulenequinones: Regioselective [4 + 2] and [2 + 2] Cycloadditions of Benzopentalenequinone Derivative and Alkynes Bearing an Aniline Moiety
​S.-i. Kato, T. Kijima, Y. Shiota, T. Yoshihara, S. Tobita, K. Yoshizawa, Y. Nakamura,* Tetrahedron Lett. 2016, 57, 4604.
DOI: 10.1016/j.tetlet.2016.09.002

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Synthesis, Self-Association, and Anion Recognition of Conjugated Macrocycles Composed of Carbazole and Triazolium Moieties
S. Jin, S.-i. Kato, Y. Nakamura,* Chem. Lett. 2016, 45, 869.
DOI: 10.1246/cl.160400
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Synthesis and Electronic, Optical, and Electrochemical Properties of a Series of Tetracyanobutadiene-Substituted Carbazoles
S.-i. Kato, H. Noguchi, S. Jin, Y. Nakamura,* Asian J. Org. Chem. 2016, 5, 246.
DOI: 10.1002/ajoc.201500431

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2015年

Series of Carbazole‒Pyrimidine Conjugates: Synthesis and Electronic, Photophysical, and Electrochemical Properties 
S.-i. Kato, Y. Yamada, H. Hiyoshi, K. Umezu, Y. Nakamura,* J. Org. Chem. 2015, 80, 9076. 
DOI: 10.1021/acs.joc.5b01409

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A Series of π-Extended Thiadiazoles Fused with Electron-Donating Heteroaromatic Moieties: Syntheses, Properties, and Polymorphic Crystals
S.-i. Kato, T. Furuya, M. Nitani, N. Hasebe, Y. Ie, Y. Aso, T. Yoshihara, S. Tobita, Y. Nakamura,* Chem. Eur. J. 2015, 21, 3115. 
DOI: 10.1002/chem.201405478
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2014年
Systematic Structure‒Property Investigations on a Series of Alternating Carbazole‒Thiophene Oligomers
S.-i. Kato, S. Shimizu, A. Kobayashi, T. Yoshihara, S. Tobita, Y. Nakamura,* J. Org. Chem. 2014, 79, 618.
DOI: 10.1021/jo402416f
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2013年
Hexadecadehydrodibenzo[20]-, Tetracosadehydrotribenzo[30]-, and Dotriacontadehydrotetrabenzo[40]annulenes: Syntheses, Characterizations, Electronic Properties, and Self-Associations
S.-i. Kato, N. Takahashi, Y. Nakamura,* J. Org. Chem. 2013, 78, 7658.   
DOI: 10.1021/jo401200m
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Tetraalkoxyphenanthrene-Fused Dehydroannulenes: Synthesis, Self-Assembly, and Electronic, Optical, and Electrochemical Properties
S.-i. Kato, N. Takahashi, H. Tanaka, A. Kobayashi, T. Yoshihara, S. Tobita, T. Yamanobe, H. Uehara, Y. Nakamura,* Chem. Eur. J. 2013, 19, 12138.  
DOI: 10.1002/chem.201301262
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Synthesis and Properties of Disiloxane-bridged Cyclophanes Bearing Heteroaromatics
S.-i. Kato, N. Yamazaki, T. Tajima, Y. Nakamura,* Chem. Lett. 2013, 42, 401.  
DOI: org/10.1246/cl.2013.401
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Photochemical Behaviors of a Tethered 1,3-Diketone Derivative Studied by Transient Absorption and Time-resolved EPR Measurements
Atsushi Kobayashi, Minoru Yamaji,* Satoru Nakajima, Kimio Akiyama, Shozo Tero-Kubota, Shin-ichiro Kato, Yosuke Nakamura,
Chem. Phys. Lett. 2013, 555, 101.
DOI:10.1016/j.cplett.2012.10.067
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2012年

Bicarbazoles: Systematic Structure-Property Investigations on a Series of Conjugated Carbazole Dimers
S.-i. Kato, H. Noguchi, A. Kobayashi, T. Yoshihara, S. Tobita, Y. Nakamura,* J. Org. Chem. 2012, 77, 9120. 
DOI: 10.1021/jo3016538
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π-Extended Thiadiazoles Fused with Thienopyrrole or Indole Moieties: Synthesis, Structures, and Properties
S.-i. Kato, T. Furuya, A. Kobayashi, M. Nitani, Y. Ie, Y. Aso, T. Yoshihara, S. Tobita, Y. Nakamura,* J. Org. Chem. 2012, 77, 7595.
DOI: 10.1021/jo301458m
Highlighted in SYNFACTS
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Synthesis and Electronic, Photophysical, and Electrochemical Properties of a Series of Thienylcarbazoles
S.-i. Kato, S. Shimizu, H. Taguchi, A. Kobayashi, S. Tobita, Y. Nakamura,* J. Org. Chem. 2012, 77, 3222.
DOI: 10.1021/jo202625p
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2011年

Synthesis of [60]Fullerene-Containing [2]Rotaxanes Using Axle Molecules Bearing Donor Moiety
Y. Kasai, C. Sakamoto, N. Muroya, S.-i. Kato, Y. Nakamura,* Tetrahedron Lett. 2011, 52, 623.
DOI: 10.1016/j.tetlet.2010.11.155
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2009年

Synthesis and Photophysical Properties of N-Arylcarbazolophanes
H. Shimizu, Y. Kakinoya, K. Takehira, T. Yoshihara, S. Tobita, Y. Nakamura,* J. Nishimura, Bull. Chem. Soc. Jpn. 2009, 82, 860.

DOI: 10.1246/bcsj.82.860
Substituent Effects on Photophysical Properties of N-Thienylcarbazoles
H. Shimizu, A. Kobayashi, S. Itoi, T. Yoshihara, S. Tobita, Y. Nakamura,* J. Nishimura, Heterocycles 2009, 78, 1256.
DOI: 10.3987/COM-08-11613
Kinetic Study on Huisgen Reaction Catalyzed by Copper(I): Triazol Formation from Water-Soluble Alkyne and Alkyl Azide
Y. Kasuga, M. Ito, W. Onoda, Y. Nakamura, S. Inokuma, T. Matsuda, J. Nishimura,* Heterocycles 2009, 78, 983.
DOI: 10.3987/COM-08-11592


総説

2013年

カルバゾール等の複素環を基盤とするπ共役系化合物の合成と物性
中村 洋介,* 加藤 真一郎, 野口 裕冬, 有機合成化学協会誌, 2013, 71, 779.

2011年

Exohedral Functionalization of Fullerenes and Supramolecular Chemistry
Y. Nakamura,* S.-i. Kato, Chem. Rec. 2011, 11, 77.
DOI: 10.1002/tcr.201000036

Copyright: Nakamura's group. All rights reserved.
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